SAFETY DATA SHEET
1. Identification
Product identifier NIKE S75 XXL (WM-7698)
Other means of identification
Brand Code
200C
Recommended use
For Industrial Use Only
Recommended restrictions
Users should be informed of the potential presence of respirable dust and respirable crystalline
silica as well as their potential hazards. Appropriate training in the proper use and handling of this
material should be provided as required under applicable regulations.
Manufacturer/Supplier information
Manufacturer
Telephone
General Phone: 412-375-6600
Moon Township, Pennsylvania 15108 US
HarbisonWalker International
Address
Emergency phone number
CHEMTREC 24 HOUR
EMERGENCY #
1-800-424-9300
1305 Cherrington Parkway, Suite 100
Company name
Website
www.thinkHWI.com
2. Hazard(s) identification
Classified hazards
This item is defined as an article per OSHA (29 CFR 1910.1200) and is therefore exempt from labeling. A Safety Data Sheet is
available.
This item is not hazardous per OSHA 29 CFR 1910.1200(c). However, individual customer processes (such as grinding, sawing,
or blasting) may result in the formation of dust that may present health hazards. May cause respiratory irritation, lung injury, or
cancer by inhalation. Limit skin contact. Wash hands after handling. Dispose of waste and residues in accordance with local
authority requirements. Wear protective gloves/protective clothing/eye protection. Dust may cause cancer.
Label elements
This item is defined as an article per OSHA (29 CFR 1910.1200) and is therefore exempt from labeling. A Safety Data Sheet is
available.
This item is not hazardous per OSHA 29 CFR 1910.1200(c). However, individual customer processes (such as grinding, sawing,
or blasting) may result in the formation of dust that may present health hazards. May cause respiratory irritation, lung injury, or
cancer by inhalation. Limit skin contact. Wash hands after handling. Dispose of waste and residues in accordance with local
authority requirements. Wear protective gloves/protective clothing/eye protection. Dust may cause cancer.
Hazard(s) not otherwise classified (HNOC)
This item is defined as an article per OSHA (29 CFR 1910.1200) and is therefore exempt from labeling. A Safety Data Sheet is
available.
This item is not hazardous per OSHA 29 CFR 1910.1200(c). However, individual customer processes (such as grinding, sawing,
or blasting) may result in the formation of dust that may present health hazards. May cause respiratory irritation, lung injury, or
cancer by inhalation. Limit skin contact. Wash hands after handling. Dispose of waste and residues in accordance with local
authority requirements. Wear protective gloves/protective clothing/eye protection. Dust may cause cancer.
3. Composition/information on ingredients
Mixtures
CAS number %Chemical name Common name and synonyms
12183-80-1Andalusite (Al2O(SiO4))
40 - 60
1344-28-1Aluminium Oxide (Non-Fibrous)
20 - 40
1332-58-7Kaolin
2.5 - 10
Other components below reportable levels 2.5 - 10
14808-60-7Quartz (SiO2)
2.5 - 10
*Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret.
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Material name: NIKE S75 XXL (WM-7698)
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4. First-aid measures
Inhalation
Move to fresh air. Call a physician if symptoms develop or persist.
Skin contact
Wash off with soap and water. Get medical attention if irritation develops and persists.
Eye contact
Rinse with water. Get medical attention if irritation develops and persists.
Ingestion
Rinse mouth. Get medical attention if symptoms occur.
Most important
symptoms/effects, acute and
delayed
Direct contact with eyes may cause temporary irritation.
Indication of immediate
medical attention and special
treatment needed
Provide general supportive measures and treat symptomatically. Keep victim under observation.
Symptoms may be delayed.
General information
If concerned: Get medical advice. Ensure that medical personnel are aware of the material(s)
involved, and take precautions to protect themselves.
5. Fire-fighting measures
Suitable extinguishing media
Use fire-extinguishing media appropriate for surrounding materials.
Unsuitable extinguishing
media
Not available.
Specific hazards arising from
the chemical
Not applicable.
Special protective equipment
and precautions for firefighters
Not available.
6. Accidental release measures
Personal precautions,
protective equipment and
emergency procedures
Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Wear
appropriate protective equipment and clothing during clean-up. Ensure adequate ventilation. Local
authorities should be advised if significant spillages cannot be contained. For personal protection,
see section 8 of the SDS.
Methods and materials for
containment and cleaning up
Stop the flow of material, if this is without risk. Following product recovery, flush area with water.
For waste disposal, see section 13 of the SDS.
Environmental precautions
Avoid discharge into drains, water courses or onto the ground.
7. Handling and storage
Precautions for safe handling
Obtain special instructions before use. Do not handle until all safety precautions have been read
and understood. Keep formation of airborne dusts to a minimum. Provide appropriate exhaust
ventilation at places where dust is formed. Do not breathe dust. Do not breathe dust. Avoid
prolonged exposure. Should be handled in closed systems, if possible. Wear appropriate personal
protective equipment. Observe good industrial hygiene practices.
Conditions for safe storage,
including any incompatibilities
Store locked up. Store in original tightly closed container. Store away from incompatible materials
(see Section 10 of the SDS).
8. Exposure controls/personal protection
Occupational exposure limits
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
ValueComponents
Form
Type
PEL 5 mg/m3 Respirable fraction.Aluminium Oxide
(Non-Fibrous) (CAS
1344-28-1)
15 mg/m3 Total dust.
PEL 5 mg/m3 Respirable fraction.Kaolin (CAS 1332-58-7)
15 mg/m3 Total dust.
US. OSHA Table Z-3 (29 CFR 1910.1000)
ValueComponents
Form
Type
TWA 0.3 mg/m3 Total dust.Quartz (SiO2) (CAS
14808-60-7)
0.1 mg/m3 Respirable.
2.4 mppcf Respirable.
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Material name: NIKE S75 XXL (WM-7698)
200C Version #: 01 Issue date: 05-13-2015
SDS US
US. ACGIH Threshold Limit Values
ValueComponents
Form
Type
TWA 1 mg/m3 Respirable fraction.Aluminium Oxide
(Non-Fibrous) (CAS
1344-28-1)
TWA 1 mg/m3 Respirable fraction.Andalusite (Al2O(SiO4))
(CAS 12183-80-1)
TWA 2 mg/m3 Respirable fraction.Kaolin (CAS 1332-58-7)
TWA 0.025 mg/m3 Respirable fraction.Quartz (SiO2) (CAS
14808-60-7)
US. NIOSH: Pocket Guide to Chemical Hazards
ValueComponents
Form
Type
TWA 5 mg/m3 Respirable.Kaolin (CAS 1332-58-7)
10 mg/m3 Total
TWA 0.05 mg/m3 Respirable dust.Quartz (SiO2) (CAS
14808-60-7)
Biological limit values
No biological exposure limits noted for the ingredient(s).
Exposure guidelines
Occupational exposure to nuisance dust (total and respirable) and respirable crystalline silica
should be monitored and controlled.
Appropriate engineering
controls
Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates
should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation,
or other engineering controls to maintain airborne levels below recommended exposure limits. If
exposure limits have not been established, maintain airborne levels to an acceptable level.
Individual protection measures, such as personal protective equipment
Eye/face protection
If contact is likely, safety glasses with side shields are recommended.
Skin protection
Hand protection
Wear appropriate chemical resistant gloves.
Other
Use of an impervious apron is recommended.
Respiratory protection
Use a NIOSH/MSHA approved respirator if there is a risk of exposure to dust/fume at levels
exceeding the exposure limits.
Thermal hazards
Wear appropriate thermal protective clothing, when necessary.
General hygiene
considerations
Always observe good personal hygiene measures, such as washing after handling the material
and before eating, drinking, and/or smoking. Routinely wash work clothing and protective
equipment to remove contaminants.
9. Physical and chemical properties
Appearance
Physical state
Solid.
Form
Solid
Color
Not available.
Odor
Not available.
Odor threshold
Not available.
pH
Not available.
Melting point/freezing point
Not available.
Initial boiling point and boiling
range
Not available.
Flash point
Not available.
Evaporation rate
Not available.
Flammability (solid, gas)
Not available.
Upper/lower flammability or explosive limits
Flammability limit - lower
(%)
Not available.
Flammability limit - upper
(%)
Not available.
Explosive limit - lower (%)
Not available.
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Material name: NIKE S75 XXL (WM-7698)
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Explosive limit - upper (%)
Not available.
Vapor pressure
Not available.
Vapor density
Not available.
Relative density
Not available.
Solubility(ies)
Solubility (water)
Not available.
Partition coefficient
(n-octanol/water)
Not available.
Auto-ignition temperature
Not available.
Decomposition temperature
Not available.
Viscosity
Not available.
10. Stability and reactivity
Reactivity
The product is stable and non-reactive under normal conditions of use, storage and transport.
Chemical stability
Material is stable under normal conditions.
Possibility of hazardous
reactions
No dangerous reaction known under conditions of normal use.
Conditions to avoid
Contact with incompatible materials.
Incompatible materials
Acids. Powerful oxidizers. Chlorine.
Incompatibility is based strictly upon potential theoretical reactions between chemicals and may
not be specific to industrial application exposure. Contact your sales representative for
clarification.
Hazardous decomposition
products
No hazardous decomposition products are known.
11. Toxicological information
Information on likely routes of exposure
Inhalation
Prolonged inhalation may be harmful.
Skin contact
No adverse effects due to skin contact are expected.
Eye contact
Direct contact with eyes may cause temporary irritation.
Ingestion
Expected to be a low ingestion hazard.
Symptoms related to the
physical, chemical and
toxicological characteristics
Direct contact with eyes may cause temporary irritation.
Information on toxicological effects
Acute toxicity
Not available.
Skin corrosion/irritation
Prolonged skin contact may cause temporary irritation.
Serious eye damage/eye
irritation
Direct contact with eyes may cause temporary irritation.
Respiratory or skin sensitization
Respiratory sensitization
Not a respiratory sensitizer.
Skin sensitization
This product is not expected to cause skin sensitization.
Germ cell mutagenicity
No data available to indicate product or any components present at greater than 0.1% are
mutagenic or genotoxic.
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Carcinogenicity
In 1997, IARC (the International Agency for Research on Cancer) concluded that crystalline silica
inhaled from occupational sources can cause lung cancer in humans. However in making the
overall evaluation, IARC noted that "carcinogenicity was not detected in all industrial
circumstances studied. Carcinogenicity may be dependent on inherent characteristics of the
crystalline silica or on external factors affecting its biological activity or distribution of its
polymorphs." (IARC Monographs on the evaluation of the carcinogenic risks of chemicals to
humans, Silica, silicates dust and organic fibres, 1997, Vol. 68, IARC, Lyon, France.) In June
2003, SCOEL (the EU Scientific Committee on Occupational Exposure Limits) concluded that the
main effect in humans of the inhalation of respirable crystalline silica dust is silicosis. "There is
sufficient information to conclude that the relative risk of lung cancer is increased in persons with
silicosis (and, apparently, not in employees without silicosis exposed to silica dust in quarries and
in the ceramic industry). Therefore, preventing the onset of silicosis will also reduce the cancer
risk..." (SCOEL SUM Doc 94-final, June 2003) According to the current state of the art, worker
protection against silicosis can be consistently assured by respecting the existing regulatory
occupational exposure limits. May cause cancer. Occupational exposure to respirable dust and
respirable crystalline silica should be monitored and controlled.
IARC Monographs. Overall Evaluation of Carcinogenicity
Quartz (SiO2) (CAS 14808-60-7) 1 Carcinogenic to humans.
US. National Toxicology Program (NTP) Report on Carcinogens
Quartz (SiO2) (CAS 14808-60-7) Known To Be Human Carcinogen.
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
Reproductive toxicity
This product is not expected to cause reproductive or developmental effects.
Specific target organ toxicity -
single exposure
Not classified.
Specific target organ toxicity -
repeated exposure
Not classified.
Aspiration hazard
Not an aspiration hazard.
Chronic effects
Prolonged inhalation may be harmful. Prolonged exposure may cause chronic effects.
12. Ecological information
Ecotoxicity
The product is not classified as environmentally hazardous. However, this does not exclude the
possibility that large or frequent spills can have a harmful or damaging effect on the environment.
Persistence and degradability
No data is available on the degradability of this product.
Bioaccumulative potential
No data available.
Mobility in soil
No data available.
Other adverse effects
No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation
potential, endocrine disruption, global warming potential) are expected from this component.
13. Disposal considerations
Disposal instructions
This product, in its present state, when discarded or disposed of, is not a hazardous waste
according to Federal regulations (40 CFR 261.4 (b)(4)). Under RCRA, it is the responsibility of the
user of the product to determine, at the time of disposal, whether the product meets RCRA criteria
for hazardous waste.
Hazardous waste code
Not applicable.
Waste from residues / unused
products
Not available.
Contaminated packaging
Not available.
14. Transport information
DOT
Not regulated as dangerous goods.
IATA
Not regulated as dangerous goods.
IMDG
Not regulated as dangerous goods.
Not available.
Transport in bulk according to
Annex II of MARPOL 73/78 and
the IBC Code
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Material name: NIKE S75 XXL (WM-7698)
200C Version #: 01 Issue date: 05-13-2015
SDS US
15. Regulatory information
US federal regulations
This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200. All chemical substances in this product are listed on the TSCA
chemical substance inventory where required.
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
CERCLA Hazardous Substance List (40 CFR 302.4)
Not listed.
SARA 304 Emergency release notification
Not regulated.
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Hazard categories
Immediate Hazard - No
Delayed Hazard - Yes
Fire Hazard - No
Pressure Hazard - No
Reactivity Hazard - No
SARA 302 Extremely hazardous substance
Not listed.
SARA 311/312 Hazardous
chemical
No
SARA 313 (TRI reporting)
Chemical name CAS number % by wt.
Aluminium Oxide (Non-Fibrous) 1344-28-1 20 - 40
Other federal regulations
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.
Safe Drinking Water Act
(SDWA)
Not regulated.
US state regulations
US. California Controlled Substances. CA Department of Justice (California Health and Safety Code Section 11100)
Not listed.
US. Massachusetts RTK - Substance List
Aluminium Oxide (Non-Fibrous) (CAS 1344-28-1)
Kaolin (CAS 1332-58-7)
Quartz (SiO2) (CAS 14808-60-7)
US. New Jersey Worker and Community Right-to-Know Act
Aluminium Oxide (Non-Fibrous) (CAS 1344-28-1)
Kaolin (CAS 1332-58-7)
Quartz (SiO2) (CAS 14808-60-7)
US. Pennsylvania Worker and Community Right-to-Know Law
Aluminium Oxide (Non-Fibrous) (CAS 1344-28-1)
Kaolin (CAS 1332-58-7)
Quartz (SiO2) (CAS 14808-60-7)
US. Rhode Island RTK
Aluminium Oxide (Non-Fibrous) (CAS 1344-28-1)
US. California Proposition 65
WARNING: This product contains a chemical known to the State of California to cause cancer.
US - California Proposition 65 - CRT: Listed date/Carcinogenic substance
Quartz (SiO2) (CAS 14808-60-7) Listed: October 1, 1988
International Inventories
Country(s) or region Inventory name On inventory (yes/no)*
NoAustralia Australian Inventory of Chemical Substances (AICS)
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Country(s) or region Inventory name On inventory (yes/no)*
NoCanada Domestic Substances List (DSL)
YesCanada Non-Domestic Substances List (NDSL)
NoChina Inventory of Existing Chemical Substances in China (IECSC)
NoEurope European Inventory of Existing Commercial Chemical
Substances (EINECS)
NoEurope European List of Notified Chemical Substances (ELINCS)
NoJapan Inventory of Existing and New Chemical Substances (ENCS)
YesKorea Existing Chemicals List (ECL)
YesNew Zealand New Zealand Inventory
NoPhilippines Philippine Inventory of Chemicals and Chemical Substances
(PICCS)
YesUnited States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory
*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)
A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
country(s).
16. Other information, including date of preparation or last revision
Issue date
05-13-2015
Version #
01
Disclaimer
This information is based on our present knowledge on creation date. However, this shall not
constitute a guarantee for any specific product features and shall not establish a legally valid
contractual relationship.
Revision Information
Product and Company Identification: Product and Company Identification
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Material name: NIKE S75 XXL (WM-7698)
200C Version #: 01 Issue date: 05-13-2015
SDS US
